She's not eligible to break Kelly's record because she didn't debut on the Hot 100 already. She would have had to be at #98 or #99 or #100. Bubbling Under doesn't count.
"'I Will Be' is a song I have known for a while… From the outside looking in I know that everyone was fighting for Avril to put this on her record but for reasons I will not disclose, Avril, did not... I remember Luke playing this song for me months ago and I was at the point of tears knowing I heard a song that would be the hugest thing ever… I mean, people, be prepared to hear this song at EVERY WEDDING for a LONG time."